1,3,5-ADAMANTANETRIOL /CAS：99181-50-7

Whakamahinga

He pai te pumau matū o te 1,3,5-Adamantanetriol, ā, kāore e ngāwari ki ngā tauhohenga matū i raro i ngā āhuatanga noa. Ko te tauhohenga matū o tēnei matū e aro nui ana ki ngā rōpū hydroxyl hohe e toru i roto i tōna hanganga, ā, he rite ngā wāhi tauhohenga matū o ēnei waeine hydroxyl e toru. Ahakoa e toru ngā rōpū hydroxyl ōrite, kua whakaatuhia e ētahi rangahau ka taea te whiriwhiri i tētahi o ngā rōpū hydroxyl ki te tauhohenga halogenation, ā, ka whakaurua ngā rōpū mahi rerekē ki roto i te ngota hei whakawhānui ake i tōna kanorau matū. Hei tāpiri, nā te nucleophilicity o ngā rōpū hydroxyl, ka taea e tēnei matū te whai i te tauhohenga acylation me ngā pūhui acyl chloride hei whiwhi i ngā hua ester e rite ana.

Ko te 1,3,5-Adamantanetriol te mea e whakamahia nuitia ana hei matū taketake mō te hanga matū waro, ā, e whakamahia ana i roto i ngā rangahau matū waro taketake. Nā te nui o te aukati steric o ngā ngota waro i runga i te mowhiti adamantane i roto i te 1,3,5-adamantanetriol, he āhuatanga motuhake ōna i roto i te hanga matū waro. Ka taea te whakamahi i tēnei āhuatanga aukati steric nui mō te whakarerekētanga hanganga me te hanga matū waro. I roto i te hanga matū waro, ka taea e ngā rōpū aukati steric nui te pā ki te regioselectivity me te enantioselectivity o ngā tauhohenga, ā, he pai ngā tono i roto i ngā rangahau matū taketake mō te catalysis kore-taurite.

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