1,3,5-ADAMANTANETRIOL /CAS：99181-50-7

Hoʻohana

He kūpaʻa kemika maikaʻi ko 1,3,5-Adamantanetriol a ʻaʻole ia e maʻalahi i nā hopena kemika ma lalo o nā kūlana maʻamau. ʻO ka hana kemika o kēia mea e kau nui ʻia ana ma luna o nā hui hydroxyl ʻekolu i loko o kona ʻano, a he mau wahi hopena like kemika kēia mau ʻāpana hydroxyl ʻekolu. ʻOiai he ʻekolu mau hui hydroxyl like, ua hōʻike kekahi mau noiʻi e hiki ke koho ʻia kekahi o nā hui hydroxyl i kahi hopena halogenation, no laila e hoʻokomo i nā hui hana like ʻole i loko o ka mole e hoʻonui i kona ʻano kemika. Eia kekahi, ma muli o ka nucleophilicity o nā hui hydroxyl, hiki i kēia mea ke hana i kahi hopena acylation me nā hui acyl chloride e loaʻa ai nā derivatives ester like.

Hoʻohana nui ʻia ʻo 1,3,5-Adamantanetriol ma ke ʻano he reagent kumu no ka synthesis organik a hoʻohana ʻia i ka noiʻi kemika organik kumu. Ma muli o ka nui o ke ālai ʻana o ka steric o nā ʻātoma kalapona ma ke apo adamantane i loko o 1,3,5-adamantanetriol, loaʻa iā ia kekahi mau ʻano kikoʻī i ka synthesis organik. Hiki ke hoʻohana ʻia kēia waiwai ālai steric nui no ka hoʻololi ʻana i ke ʻano a me ka synthesis o nā ligands organik. I ka synthesis organik, hiki i nā hui ālai steric nui ke hoʻopilikia i ka regioselectivity a me ka enantioselectivity o nā hopena a he mau noi maikaʻi i ka noiʻi kemika kumu ma ka catalysis asymmetric.

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